Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes
نویسندگان
چکیده
منابع مشابه
Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes.
We have prepared the first examples of B9-connected trivalent aryl and alkyl phosphinoborane species via Pd-catalyzed phosphination of 9-iodo-meta-carborane. Our studies highlight the unique electronic features of the B9-connected meta-carboranyl moiety as compared to its C1-based analogue. This work suggests that the B9-functionalized meta-carboranyl substituent in these ligands exhibits more ...
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für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
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General remarks on the structure and the lattice vibrations o f the different structure groups o f boron and icosahedral boron-rich borides are made. In detail, the lattice vibrations o f the alpha-rhombohedral boron structure group are systematically investigated by group theory. Reflectivity spectra o f boroncarbide o f different chemical com position and preparation and o f B60 were measured...
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ژورنال
عنوان ژورنال: Organometallics
سال: 2012
ISSN: 0276-7333,1520-6041
DOI: 10.1021/om301116x